Tom Hiddleston as Loki (Thor, Avengers)
Thomas William Hiddleston is an English actor. He is best known for his role as Loki in the Marvel Cinematic Universe, appearing in Thor, The Avengers, and Thor: The Dark World.
Actually before I came to this list I knew he already won. you dang fangirls.
Cute Dimpples. Might interveiwe him soon. - LokiLaufeyson2000
Ian McKellen as Erik Lensherr/Magneto (X-Men Trilogy)
Sir Ian Murray McKellen is an English actor. He is the recipient of six Laurence Olivier Awards, a Tony Award, a Golden Globe Award, a Screen Actors Guild Award, a BIF Award, two Saturn Awards, four Drama Desk Awards and two Critics' Choice Awards.
Come on people. He's PERFECT!
Alfred Molina as Otto Octavius/Doctor Octopus (Spider-Man 2)
Hugo Weaving as Johann Schmidt (Captain America)
He sounded just like Werner Herzog, the man is incredible... - KnutHudson
Tim Roth as Emil Blonsky/Abomination (The Incredible Hulk)
Michael Fassbender as Erik Lensherr/Magneto (X-Men: First Class, X-Men: Days of Future Past)
Michael Fassbender is a German-Irish actor of stage and screen whose career includes roles in both independent and blockbuster films, most notably; Hunger, Inglourious Basterds, Shame, X-Men: First Class, Prometheus, 12 Years a Slave, Frank, X-Men: Days of Future Past, and Steve Jobs.
What, down at 18th? I like Sir Ian, too, but Fassbender did a great job as the "angry young man" version of the character, too. - KnutHudson
Rebecca Romijn as Raven Darkhölme/Mystique (X-Men Trilogy)
Aaron Stanford as John Allerdyce/Pyro (X-Men: The Last Stand)
Wasn't a villain until X-Men: The Last Stand
Stephen Dorff as Deacon Frost (Blade)
Dominic West as Billy Russoti/Jigsaw (Punisher: War Zone)
Julian McMahon as Doctor Doom (Fantastic Four Series)
Julian Dana William McMahon (born 27 July 1968) is an Australian actor and model, and the son of a former Prime Minister of Australia, Sir William McMahon. ...read more.
Liev Schreiber as Victor Creed/Sabretooth
Topher Grace as Eddie Brock/Venom (Spider-Man 3)
What? No. Just, no. - KnutHudson
Colin Farrell as Bullseye (Daredevil)
William Dafoe as Norman Osborn/Green Goblin (Spider-Man)
Thomas Haden Church as Flint Marko/Sandman (Spider-Man 3)
Michael Clarke Duncan as Wilson Fiske/Kingpin (Daredevil)
Michael Clarke Duncan was an American actor, best known for his breakout role as John Coffey in The Green Mile, for which he was nominated for the Academy Award for Best Supporting Actor and various similar honors.
Jennifer Lawrence as Raven Darkhölme/Mystique (X-Men: First Class, X-Men: Days of Future Past)